Chapter 13 - glossary

 

adsorbable organically bound halogens, AOX
fraction of the halogenated organic compound which can be adsorbed to activated carbon and thus is easily quantified

bioaccumulation
accumulation of fat-soluble and stable pollutants in fat tissues in animals, typically fat, liver and brain in man, egg yolk in birds, and mothers milk

biochemical oxygen demand, BOD7 or BOD5
the amount of oxygen used for biological decomposition during a given period of time, 7 or 5 days, used as a measure of discharged organic substance

biocides
natural or synthetic chemical compounds toxic to living organisms used to control various plants (weeds) or animals (pests); used in agriculture, forestry and horticulture

biomagnification
the increased concentration of fat-soluble and stable pollutants in the upper parts of a food chain

chromatography
method to separate individual constituents in a sample between a solid and a mobile phase during their flow in a chromatographic system

congeners
variants of a class of organic compounds that differ in e.g. the number of chlorine atoms in the basic structure

consumption emissions
emissions caused by the use and, later on, disposal of a product

dioxins
are a structurally closely related group of hydrophobic chemicals, which are persistent and bioaccumulating, and some of them extremely toxic; Dioxins are polychlorinated dibenzo-p-dioxins (PCDDs). The closely related dibenzofurans (PCDFs) have dioxin-like properties

ecological rucksack
material which is moved but not used, e.g. the overburden from mining

extractable organically bound chlorine, EOCl
fraction of chlorinated organic compound which can be the extracted in an organic solvent, such as benzene, normally used to express the biologically relevant chlorinated organic compound in organisms (e.g. in the fatty tissues of fish) and in sediments

flame retardant
substance incorporated in e.g. plastics and electronic equipment to make them resistant to fire

fluorescence spectrophotometry
method to determine certain pollutants such as benzopyrenes, naphtalenes or anthracene measuring emitted light from a sample excited by incoming light

gas chromatography, GC, or gas liquid chromatography, GLC
chromatographic method in which the mobile phase is an inert carrier gas, such as argon or helium, which transports the injected sample through a long column packed with solid beads coated with absorbent liquid

gas chromatography mass spectrometry, GC-MS
a powerful means of analysis in which gas chromatography and mass spectrometry is combined to identify substances both according to their retention time in the chromatography and the line patterns in the mass spectrometry

halogenation
incorporation of a halogen, i.e. bromine, chlorine, fluorine or iodine, in a compound

halogenated organic compounds, hydrocarbons
organic compounds in which at least a part of hydrogen atoms is replaced by fluorine, bromine or chlorine, as a means to make the compounds more stable

herbicides
toxic chemical compounds used in agriculture, forestry, and horticulture to fight weeds

high performance liquid chromatography, HPLC
chromatographic method in which the mobile phase, a solvent, is pumped through a rather short column at very high pressures

hydrocarbons
organic chemicals containing only hydrogen and carbon atoms

infrared spectrometry
method to measure by absorption of infrared light, carbon monoxide, carbon dioxide, sulphur dioxide, or organic or inorganic compounds as dust, in soil, or on leaf surfaces collected in filters or in adsorbents

insecticides
toxic chemical compounds used in agriculture, forestry and horticulture to fight insects

isomers
variants of an organic compound that have identical composition but different structures, e.g. the position of chlorine atoms in the molecule

life-cycle assessment
a "cradle to grave" description of the environmental effects of a product including acquisition of raw materials, manufacturing, usage, maintenance, and management of the finished product (waste)

lipophilic
fat-soluble, often fatty or oily substances

liquid chromatography, LC
a low pressure column chromatographic method relying on fairly simple equipment, allowing a crude separation of samples

mass spectrometry, MS
sensitive method to identify volatile organic substances after ionisation and fragmentation, and separation in a very strong magnetic field according to mass and charge

materials intensity per service unit, MIPS
a measure of the materials used for a specified service

metabolites
substances that are produced by metabolism of pollutants in the environment, most often leading to harmless products, but the metabolites may be more persistent and also more toxic than the original compound

organophosphate
toxic chemical compounds used as insecticides which do not accumulate in the environment, but are quite toxic also to humans, and animals and thus more dangerous to use

persistent organic pollutants, POPs
a large and important group of polluting organic chemical substances, which are persistent

persistent
substances that stay in the environment a long time and are not easily degraded

pesticides
toxic chemical compounds used in agriculture, forestry, and horticulture to fight pests

polychlorinated biphenyl, PCB
a group of organochlorine compounds which are among the most toxic environmental pollutants, produced by chlorination of biphenyl, a molecule consisting of two benzene rings joined by a carbon-carbon bond

polycyclic aromatic hydrocarbons, PAH
group of organic pollutants, characterized by two or several benzene rings, well known from its toxic, carcinogenic or mutagenic features

sustainable chemistry
chemistry using resources, production processes, and products that are acceptable from the standpoint of sustainability and environmental impact

TCDD equivalent
measure to express relative toxicity of a dioxin or dibenzofuran with reference to the amount of the most toxic congenor, 2,3,7,8-TCDD, that would have the same effect

total organically bound chlorine, TOCl
a parameter used instead of AOX, but since the TOCl analysis is more time-consuming the method is becoming less and less common

thin layer chromatography, TLC
separation of a sample on a thin layer of an inert support, e.g. silica, on a glass or plastic plate

volatile organic compounds, VOC
hydrocarbons emitted to the air because of incomplete combustion of fossil fuel; sometimes methane is excluded and NMVOC, non-methane volatile organic carbon, is treated as a separate category